Athletes
| # | Athlete | G · S · B | Total | ||
|---|---|---|---|---|---|
| 1 | Yaroslava Mahuchikh Women · 2017–26 | 19 Sep 2001 | High jump | 19 gold 3 silver 3 bronze | 25 |
| 2 | Mykhaylo Kokhan Men · 2017–26 | 22 Jan 2001 | Hammer throw, Hammer throw (6 kg), Hammer throw (5 kg) | 14 gold 2 silver 4 bronze | 20 |
| 3 | Sergey Lebid Men · 1997–2011 | 15 Jul 1975 | 5000m, 10,000m, Senior race +1 | 13 gold 4 silver 6 bronze | 23 |
| 4 | Olha Saladukha Women · 2005–19 | 4 Jun 1983 | Triple jump | 11 gold 3 silver 3 bronze | 17 |
| 5 | Hanna Ryzyhkova-Yaroshchuk Women · 2007–22 | 24 Nov 1989 | 400m, 400m hurdles, relays | 9 gold 9 silver 2 bronze | 20 |
| 6 | Mariya Ryemyen Women · 2009–13 | 2 Aug 1987 | 60m, 200m, relays | 8 gold 2 silver 3 bronze | 13 |
| 7 | Nataliya Pohrebnyak Women · 2007–15 | 19 Feb 1988 | 100m, 200m, relays | 7 gold 6 silver 2 bronze | 15 |
| 8 | Vira Rebryk Women · 2005–13 | 25 Feb 1989 | Javelin throw | 7 gold 6 silver 1 bronze | 14 |
| 9 | Oleksandr Pohorilko Men · 2020–26 | 16 Apr 2000 | 400m, relays | 7 gold 3 silver 4 bronze | 14 |
| 10 | Bohdan Bondarenko Men · 2005–16 | 30 Aug 1989 | High jump | 7 gold 2 silver 2 bronze | 11 |
| 11 | Yuriy Bilonog Men · 1991–2007 | 9 Mar 1974 | Shot put, Shot put (6 kg) | 7 gold 1 silver 5 bronze | 13 |
| 12 | Maryna Bekh-Romanchuk Women · 2011–23 | 18 Jul 1995 | Long jump, Triple jump | 6 gold 4 silver 4 bronze | 14 |
| 13 | Vita Pavlysh Women · 1994–2003 | 15 Jan 1969 | Shot put | 6 gold 3 silver 2 bronze | 11 |
| 14 | Olesya Povh Women · 2010–13 | 18 Oct 1987 | 60m, 100m, relays | 6 gold 3 silver 2 bronze | 11 |
| 15 | Artur Felfner Men · 2019–25 | 17 Oct 2003 | Javelin throw, Javelin throw (700 g) | 6 gold 2 silver 2 bronze | 10 |
| 16 | Serhiy Smelik Men · 2013–21 | 19 Apr 1987 | 200m, relays | 6 gold 0 silver 3 bronze | 9 |
| 17 | Alina Shukh Women · 2015–20 | 12 Feb 1999 | Javelin throw, Heptathlon, Heptathlon (U18) | 6 gold 0 silver 2 bronze | 8 |
| 18 | Valeriy Borzov Men · 1971–75 | 20 Oct 1949 | 100m, 200m, relays | 6 gold 0 silver 0 bronze | 6 |
| 19 | Zhanna Pintusevich-Block Women · 1991–2001 | 6 Jul 1972 | 60m, 100m, 200m +1 | 5 gold 7 silver 2 bronze | 14 |
| 20 | Mykyta Nesterenko Men · 2006–22 | 15 Apr 1991 | Shot put (6 kg), Discus throw, Discus throw (1.75 kg) +1 | 5 gold 4 silver 3 bronze | 12 |
| 21 | Oleksandr Bagach Men · 1993–99 | 21 Nov 1966 | Shot put | 5 gold 2 silver 4 bronze | 11 |
| 22 | Yana Hladiychuk Women · 2020–25 | 21 May 1993 | Pole vault | 5 gold 1 silver 1 bronze | 7 |
| 23 | Olga Bryzgina Women · 1983–91 | 30 Jun 1963 | 400m, relays | 5 gold 0 silver 1 bronze | 6 |
| 24 | Danylo Danylenko Men · 2019–25 | 10 Oct 1994 | 400m, relays | 5 gold 0 silver 1 bronze | 6 |
| 25 | Mariya Pinigina Women · 1979–83 | 9 Feb 1958 | 400m, relays | 5 gold 0 silver 0 bronze | 5 |
Only international medals count: national championship titles are left out.